Pyro without fire: synthesis, structure, and reactivity of a dimeric vanadyl pyrophosphate coordination complex.
نویسندگان
چکیده
The complex {[(V(IV)O)bipy(H(2)O)](2)(μ-P(2)O(7))}·3H(2)O (2) was readily obtained as a nanocrystalline powder by one-pot synthesis under mild conditions. Single crystals of 2 were grown at room temperature over 2 months, and its structure was determined. Fundamental catalytic activity was proven for this species by testing for oxidation of benzyl alcohol in air.
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عنوان ژورنال:
- Inorganic chemistry
دوره 51 19 شماره
صفحات -
تاریخ انتشار 2012